1,4-Benzoquinone, commonly known as para-quinone, is a chemical compound with the formula C6H4O2. In a pure state, it forms bright-yellow crystals with a characteristic irritating odor, resembling that of chlorine, bleach, and hot plastic. This six-membered ring compound is the oxidized derivative of 1,4-hydroquinone. The molecule is multifunctional it exhibits properties of a ketone, forming an oxime; an oxidant, forming the dihydroxy derivative; and an alkene, undergoing addition reactions, especially those typical for α ,β -unsaturated ketones. 1,4-Benzoquinone is sensitive toward both strong mineral acids and alkali, which cause condensation and decomposition of the compound.
Appearance & Physical State
yellow to green crystalline solid
Density
1.318
Melting Point
112-116ºC
Boiling Point
293ºC
Flash Point
38ºC
Refractive Index
n20/D 1.453
Water Solubility
10 g/L (25 ºC)
Stability
Stable, but light sensitive. Incompatible with strong oxidizing agents. Flammable.
Intermediates of Dyes and Pigments; Benzoquinones, etc.
(Charge Transfer Complexes); Charge Transfer Complexes for Organic Metals; Benzoquinones; Functional Materials
mp :
113-115 °C(lit.)
bp :
293°C
density :
1.31
vapor density :
3.73 (vs air)
vapor pressure :
0.1 mm Hg ( 25 °C)
refractive index :
n20/D 1.453
Fp :
38°C
storage temp. :
2-8°C
Water Solubility :
10 g/L (25 ºC)
Merck :
14,8074
BRN :
773967
Stability:
; Stable, but light sensitive. Incompatible with strong oxidizing agents. Flammable.
1,4-Benzoquinone/para-benzoquinone/PBQ/P-benzoquinone CAS 106-51-4
It can be used as dye and pharmaceutical intermediates, rubber protective agent, inhibitor, antioxidants, developer, and so on。The application as following:
1.Can be used as Pesticide intermediates, such as Ethofumesate
2.As Pharmaceutical intermediates, such as Etamsylate
3.As raw material for Flame retardants
4.Used at resin as Polymerization inhibitor
5.Also can be used at Petrifaction,especially for the product of Poly(vinyl alcohol),the PBQ has great effect as inhibitor for the product.
6.Dye intermediate
Item Specifications Results
Appearance Yellow crystal powder Yellow crystal powder
Content ≥99.0% 99.53%
Melting point 112.0-116.0℃ 113.0-113.6℃
Ash ≤0.05% 0.03%
Loss on drying ≤0.5% 0.28%
Conclusion The results conforms with enterprise standards